高温高压光学浮区炉

高温高压光学浮区炉


德国ScIDre公司推出的高温高压光学浮区法单晶炉能够提供2200–3000℃以上的生长温度,晶体生长腔大压力可达300bar,甚10-5mbar的高真空。适用于生长各种超导材料单晶,介电和磁性材料单晶,氧化物及金属间化合物单晶等。

 


应用领域


适用于生长各种超导材料单晶,介电和磁性材料单晶,氧化物及金属间化合物单晶等。

可实现2600°C及以上高温(高可达3000°C);多种压力规格可选,高压力可达300bar;适用于多种材料的优质单晶生长

耐高温、耐高压、高真空、

高透光率、拆装简便的样品腔


由德国弗劳恩霍夫应用光

和精密工程研究所优化设计的高反射率镜面,

镜体位置可由高精度步进马达控制调节


光阑式光强控制器

更方便地调节熔区温度,延长灯泡寿命 


仿真化触屏控制软件

界面友好,操作简单


熔区测温选件测温技术

可实时监测加热区温度


多路独立气路控制选件

可控制N2、O2、Ar、空气等的流量和压力, 

并可对气体进行比例混合与熔区进行反应


气体除杂选件

可使高压氩气中的氧含量达到10-12ppm


退火选件

可对离开熔区的单晶棒提供

高1100℃退火温度和高压氧环境



ScIDre单晶炉特点


► 采用垂直式光路设计

► 采用高照度短弧氙灯,多种功率规格可选

► 熔区温度:>3000℃

► 熔区压力:10bar/50bar/100bar/150bar/300bar等多种规格可选

► 氧气/氩气/氮气/空气/混合气等多种气路可选

► 采用光栅控制技术,加热功率从0-100% 连续可调

► 样品腔可实现低10-5mbar真空环境

► 丰富的可升级选件



ScIDre单晶炉技术参数


熔区温度:高2000 - 3000℃以上

熔区压力:大10、50、100、150、300 bar可选

熔区真空:1*10-2 mbar或 1*10-5 mbar可选

熔区气氛:Ar、O2、N2等可选

气体流量:0.25 – 1 L/min流量可控

氙灯功率:3kW15kW可选

料棒台尺寸:6.8mm或9.8mm可选

拉伸速率:0.1-50mm/h

调节速率:0.6 mm/s

拉伸尺寸:130mm,150mm,195mm可选

旋转速率:0-70rpm

用电功率:400V三相 63A 50Hz 

主机尺寸:330cm*163cm*92cm (不同规格略有差异)



■  锂离子电池领域新应用


锂离子电池由于具有能量密度高、寿命长、充电快、安全可靠、绿色环保等诸多优异性能,与当今人民的日常生活已密不可分,在手机、电脑、电动车、电动汽车、航空航天等领域均有广泛的应用。其中,Li2FeSiO4作为新一代锂离子电池阴极材料,由于具有价格低廉、环境友好、安全性好等优势,在大型动力锂离子电池应用方面具有良好的前景。然而,Li2FeSiO4材料在不同温度具有不同的结构相(∼ 400 °C :Pmn21,  ∼ 700 °C :P121/n1, and ∼ 900 °C :Pmnb),因此,研究其不同结构的电化学性质对于进一步对其进行改性研究尤为重要。

 

Waldemar Hergetta等人[1]采用高压光学浮区法获得了高温相(Pmnb)Li2FeSiO4单晶,并研究了晶体生长工艺参数对杂相的影响,相关结果已发表在Journal of Crystal Growth。作者所采用的高压光学浮区炉为德国SciDre公司的HKZ高压光学浮区法单晶炉


温度梯度分布[1]

XRD图谱及晶体实物图片[1]


参考文献:

[1]. Waldemar Hergett, Christoph Neef, Hans-Peter Meyer, Rüdiger Klingeler, Challenges in the crystal growth of Li2FeSiO4, Journal of Crystal Growth, Volume 556, 2021, 125995,ISSN 0022-0248.



■  CoGeO3 单晶生长和性能研究


参考文献:Single Crystal Growth and Physical Properties of Pyroxene CoGeO3 Crystals 2021, 11, 378.

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2. (2020)Anisotropic character of the metal-to-metal transition in Pr4Ni3O10   Phys. Rev. B 101, 104104

3. (2020)Synthesis of a New Ruthenate Ba26Ru12O57 Crystals 2020, 10(5), 355

4. (2020)Synthesis and characterization of bulk Nd1−xSrxNiO2 and Nd1−xSrxNiO3  Phys. Rev. Materials 4, 084409

5. (2020)Magnetic phase diagram and magnetoelastic coupling of NiTiO3 Phys. Rev. B 101, 195122

6. (2019)High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3 Crystals 2019, 9(7), 324

7. (2019)Magnetic properties of high-pressure optical floating-zone grown LaNiO3 single crystals Journal of Crystal Growth Volume 524, 15 October 2019, 125157

8. (2019)Bulk single-crystal growth of the theoretically predicted magnetic Weyl semimetals RAlGe (R = Pr, Ce) Phys. Rev. Materials 3, 024204

9. (2019)Pushing boundaries: High pressure, supercritical optical floating zone materials discovery Journal of Solid State Chemistry 270 (2019): 705-709

10. (2018). Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3. Nature Communications 9:43

11. (2017). Single-crystal growth and physical properties of 50% electron-doped rhodate Sr 1.5 La 0.5 RhO 4 Physical Review Materials 1(4), 044005

12. (2017). Single crystal growth and structural evolution across the 1st order valence transition in (Pr1− yYy) 1− xCaxCoO3-δJournal of Solid State Chemistry 254, 69-74

13. (2017). Large orbital polarization in a metallic square-planar nickelate. Nature Physics 13, 864–869

14. (2017). High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO3 Single Crystals. Crystal Growth & Design 17(5), 2730-2735.

15. (2017). High-pressure optical floating-zone growth of Li(Mn,Fe)PO4 single crystals. Journal of Crystal Growth, 462, 50-59.

16. (2016). Evidence for a spinon Fermi surface in a triangular-lattice quantum-spin-liquid candidate. Nature 540, 559–562.

17. (2016). Stacked charge stripes in quasi-2D trilayer nickelate La4Ni3O8. PNAS 2016 113 (32) 8945-8950.

18. (2016). Single Crystal Growth of Pure Co3+ Oxidation State Material LaSrCoO4. Crystals, 6(8), 98.

19. (2015). Floating zone growth of Ba-substituted ruthenate Sr2−xBaxRuO4. Journal of Crystal Growth, 427, 94-98.

20. (2015). High pressure floating zone growth and structural properties of ferrimagnetic quantum paraelectric BaFe12O19. APL Materials 3, 062512.

21. (2015). Impact of local order and stoichiometry on the ultrafast magnetization dynamics of Heusler compounds. Journal of Physics D: Applied Physics, 48(16), 164016.

22. (2014). Brownmillerite Ca2Co2O5: Synthesis, Stability, and Re-entrant Single Crystal to Single Crystal Structural Transitions. Chemistry of Materials, 26(24), 7172-7182.

23. (2014). Low-temperature properties of single-crystal CrB2. Physical Review B, 90(6), 064414. (Also on archiv.org.)

24. (2014). Effect of annealing on spinodally decomposed Co2CrAl grown via floating zone technique. Journal of Crystal Growth, 401, 617-621. (Also on arxiv.org.)

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中国科学院物理研究所

中国科学院固体物理研究所

北京师范大学

中山大学

南昌大学

上海大学

北京大学

北京航空航天大学

......



单晶生长利器:高质量单晶生长设备介绍